Demonstrates the formation of rigid macrocycles in a chemical process, suggesting potential applications in materials science.
s-Aryltetrazine subunits are assembled into macrocyclic tri- and tetramers through carbon–carbon bond formation via Ullmann homocoupling of bromophenyltetrazines. Short aryl–tetrazine linkages generate compact, rigid macrocycles with small internal cavities, alongside...
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Mboyi et al. (2026) studied this question.
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