What question did this study set out to answer?

Investigate an effective palladium catalyst for cross-coupling reactions involving ortho-substituted aryl iodides and diazoesters.

A Cross-Coupling Reaction between Ortho -Substituted Aryl Iodide and Diazoester Using Tri-(2-furyl)phosphine as a Ligand of Palladium Catalyst

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Palladium-catalyzed cross-coupling generates α-diazophenyl acetate in good yields, suggesting new catalyst efficacy.

Investigate an effective palladium catalyst for cross-coupling reactions involving ortho-substituted aryl iodides and diazoesters.
Utilized palladium-complex catalysis for cross-coupling reactions.
Tested reactions with various ortho-substituted aryl iodides.
Synthesized catalysts from Pd(dba)2 and tri-(2-furyl)phosphine.
Achieved excellent yield of α-diazophenyl acetate using the optimized catalyst.
Successfully performed cross-coupling with various ortho-substituents, yielding moderate to good results.

Naoi et al. (2026) studied this question.

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