Catalytic Hydroboration of α,β-Unsaturated Ketones Using β-Diketiminate Magnesium Hydride and Mechanistic Insights

Anubhab Das; Sayantan Mukhopadhyay; Sagrika Rajput; Sharanappa Nembenna

doi:10.1039/d6dt00286b

January 1, 2026Dalton Transactions

Catalytic Hydroboration of α,β-Unsaturated Ketones Using β-Diketiminate Magnesium Hydride and Mechanistic Insights

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Key Points

The study aimed to explore hydroboration of ynones and enones using a magnesium hydride catalyst.
Catalytic hydroboration of ynones and enones
Utilization of DepNacnac stabilized magnesium hydride, Mg-1
Conducted under mild conditions
Selective hydroboration achieved
Effective catalyst: magnesium hydride
Demonstrated potential for broad application in chemical reactions

Implication

Selective hydroboration of ynones and enones using magnesium hydride showed effectiveness under mild conditions, suggesting potential for further applications.

Abstract

We report the selective hydroboration of ynones and enones catalyzed by DepNacnac stabilized magnesium hydride, Mg-1 [{LMgH}₂; L = DepNacnac = (DepNCMe)2CH; Dep = 2,6-Et2-C6H3] under mild conditions. A wide...

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Cite This Study

Das et al. (2026) studied this question.

synapsesocial.com/papers/69b4b9eb18185d8a398022c7 https://doi.org/10.1039/d6dt00286b

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Catalytic Hydroboration of α,β-Unsaturated Ketones Using β-Diketiminate Magnesium Hydride and Mechanistic Insights

Key Points

Implication

Abstract

Discussion

Cite This Study

Catalytic Hydroboration of α,β-Unsaturated Ketones Using β-Diketiminate Magnesium Hydride and Mechanistic Insights

Key Points

Implication

Abstract

Discussion

Cite This Study

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