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January 1, 2026Organic Chemistry FrontiersOpen Access

Design Principles for Enantiospecific para - and ortho -[3,3] Rearrangements of Chiral Aryl–Allyl Ethers

Johanna Breinsperger Maximilian Kaiser Peter Gärtner

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We report a systematic study that elucidates the regio-determining features of the stereoretentive para ‑Claisen–Cope and ortho -Claisen rearrangements of enantioenriched aryl–allyl ethers under mild

Abstract

We report a systematic study that elucidates the regio-determining features of the stereoretentive para ‑Claisen–Cope and ortho -Claisen rearrangements of enantioenriched aryl–allyl ethers under mild catalytic conditions. The role of the aromatic...

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Cite This Study

Breinsperger et al. (2026) studied this question.

synapsesocial.com/papers/69b5ff4f83145bc643d1b84b https://doi.org/10.1039/d6qo00040a

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