Substituent Effects in the Crystallization of Zr−Hydroxamate Metal−Organic Frameworks

Yuxin Liu; Zhen‐Wu Shao; Xiangping Duan; Chaozhi Xiong; Xiaoting Li; Chong Liu

doi:10.1039/d6ce00114a

January 1, 2026CrystEngComm

Substituent Effects in the Crystallization of Zr−Hydroxamate Metal−Organic Frameworks

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Key Points

The study investigates the impact of halogen substituents on the crystallization of Zr-hydroxamate metal-organic frameworks (MOFs).
Examined the effects of halogen substituents on Zr-hydroxamate MOFs
Analyzed changes in framework topology during crystallization
Assessed chemical robustness of the resulting structures.
Halogen substituents directed the crystallization process
Evolution from kagome to square lattice topology was observed
The first sql net was identified in this family of MOFs.

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Implication

Halogen substituent effects influence crystallization and result in square lattice topology in Zr-hydroxamate metal-organic frameworks, indicating changes in chemical robustness.

Abstract

Halogen substituent effects directed the crystallization of Zr-hydroxamate MOFs, inducing a topology evolution from kagome to square lattice—the first sql net in this MOF family—while preserving chemical robustness. In contrast,...

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Liu et al. (2026) studied this question.

synapsesocial.com/papers/69b5ff6e83145bc643d1c0b6 https://doi.org/10.1039/d6ce00114a

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Substituent Effects in the Crystallization of Zr−Hydroxamate Metal−Organic Frameworks

Key Points

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Implication

Abstract

Discussion

Cite This Study

Substituent Effects in the Crystallization of Zr−Hydroxamate Metal−Organic Frameworks

Key Points

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Implication

Abstract

Discussion

Cite This Study

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