Synthesis of α-C-Glycoside Conjugates via Giese-like Reaction Triggered by Photoactivated Electron Donor–Acceptor (EDA) Complexes and in situ photocatalytic species

Francesco Riina; Giulio Chiarello; Lorenzo Poletti; Daniele Ragno; Carmela De Risi; Mirco Natali; Federico Droghetti; Alessandro Massi; Graziano Di Carmine

doi:10.1039/d6qo00174b

January 1, 2026Organic Chemistry Frontiers

Synthesis of α-C-Glycoside Conjugates via Giese-like Reaction Triggered by Photoactivated Electron Donor–Acceptor (EDA) Complexes and in situ photocatalytic species

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Key Points

This research aims to develop methods for the efficient synthesis of α-C-glycoside conjugates using photoactivated complexes.
Utilized visible-light-mediated, catalyst-free approaches for synthesis.
Employed electron donor-acceptor (EDA) complex activation methods.
Leveraged in situ generated photocatalytic species for reactions.
Successfully synthesized α-C-glycoside conjugates via new methods.
Demonstrated the efficiency of Giese-like reactions initiated by EDA complexes.
Indicated potential for broader applications in organic synthesis.

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Implication

Innovative strategies synthesize α-C-glycosides, suggesting advanced organic chemistry techniques enhance molecular creation.

Abstract

Two visible-light-mediated, catalyst-free strategies for the synthesis of α-C-glycoside conjugates are reported. The methods exploit electron donor–acceptor (EDA) complex activation and in situ generated photocatalytically active species to trigger Giese-like...

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Riina et al. (2026) studied this question.

synapsesocial.com/papers/69bb9336496e729e62981307 https://doi.org/10.1039/d6qo00174b

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Synthesis of α-C-Glycoside Conjugates via Giese-like Reaction Triggered by Photoactivated Electron Donor–Acceptor (EDA) Complexes and in situ photocatalytic species

Key Points

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Implication

Abstract

Discussion

Cite This Study

Synthesis of α-C-Glycoside Conjugates via Giese-like Reaction Triggered by Photoactivated Electron Donor–Acceptor (EDA) Complexes and in situ photocatalytic species

Key Points

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Implication

Abstract

Discussion

Cite This Study

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