Catalytic EDA complex triggers trifluoromethylation and cyclization in hydrazones, suggesting a new reaction pathway.
Photocatalytic trifluoromethylation/cyclization of N-isopentenyl aldehyde hydrazones triggered by catalytic electron donor−acceptor (EDA) complex was developed for the construction of C5-trifluoromethylated tetrahydropyridazines. Catalytic amounts of tris(4-bromophenyl)amine was used as electron-donor and...
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Cheng et al. (2026) studied this question.
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