Demonstrates the synthesis of a novel ligand that forms a heterobimetallic complex with palladium and titanium, suggesting new applications in coordination chemistry.
A novel multidentate ligand with an O,N,O-tridentate ligand moiety and an N-heterocyclic carbene (NHC) was synthesized. Its palladium complex, in which the NHC part coordinates to the palladium atom, was synthesized and structurally characterized. The O,N,O-part coordinated to an early transition metal such as titanium. The Ti-Pd heterobimetallic complex was observed in solution.
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Suzuki et al. (2026) studied this question.
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