Se-Te Replacement Induced Structural Transition and Enhanced Band Gaps in Cd ₅ Se ₄ O ₁₂ Cl ₂ and Cd ₅ Se ₄ O ₁₂ Br ₂

Maqsood Iqbal; Jiazheng Zhou; Aqsa Munawar; Juanjuan Lu; Junjie Li

doi:10.1039/d5dt03047a

January 1, 2026Dalton Transactions

Se-Te Replacement Induced Structural Transition and Enhanced Band Gaps in Cd ₅ Se ₄ O ₁₂ Cl ₂ and Cd ₅ Se ₄ O ₁₂ Br ₂

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Key Points

To investigate how Se-Te replacement affects the structure and band gaps of specific heavy metal oxyhalides.
Synthesis of Cd5Se4O12Cl2 and Cd5Se4O12Br2 via incorporation of Se-Te replacements
Characterization of structural changes using advanced analytical techniques
Measurement of band gaps to assess photoelectric properties
Observed a structural transition in both compounds after Se-Te replacement
Increased band gaps correlated with changes in structural characteristics
Enhanced photoelectric functionality indicated by the synthesized materials' properties

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Implication

Reports the structural transition and increased band gaps in heavy metal oxyhalides, suggesting enhanced photoelectric properties.

Abstract

Heavy metal oxyhalides have emerged as promising candidates for advanced photoelectric functional materials due to their distinguished structural characteristics and properties. This study reports the synthesis and characterization of two...

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Iqbal et al. (2026) studied this question.

synapsesocial.com/papers/69be38a46e48c4981c6791f7 https://doi.org/10.1039/d5dt03047a

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Se-Te Replacement Induced Structural Transition and Enhanced Band Gaps in Cd ₅ Se ₄ O ₁₂ Cl ₂ and Cd ₅ Se ₄ O ₁₂ Br ₂

Key Points

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Implication

Abstract

Discussion

Cite This Study

Se-Te Replacement Induced Structural Transition and Enhanced Band Gaps in Cd ₅ Se ₄ O ₁₂ Cl ₂ and Cd ₅ Se ₄ O ₁₂ Br ₂

Key Points

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Abstract

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