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The study demonstrates a novel synthetic route to (±)-arnebidin, suggesting efficient biosynthesis mimicking techniques.
We report a 13-step biomimetic total synthesis of (±)-arnebidin from 1,5-dihydroxynaphthalene. An intermolecular Diels-Alder homodimerization triggers spontaneous dehydrogenation and an intramolecular cycloaddition, delivering a single diastereomer under ambient conditions. This...
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Feng et al. (2026) studied this question.
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