Octahedral tilting and B-site off-centering in halide perovskites are not coupled

Metal halide perovskites show exceptional potential for solar energy, thermoelectrics, catalysis, and other photochemical technologies, with performance rooted in electronic structure-driven properties. In ABX₃ halide perovskites, localized and often aspherical local electron densities from B-site lone pairs or polarizable X⁻ anions can distort the lattice. However, the links among electronic structure fluctuations and distortions like tilting of the BX₆ octahedra and off-centering of the B-site from the center of its octahedron are not fully understood. Using group theory and ab initio molecular dynamics, we quantify how lone pairs, halide polarization, off-centering, and octahedral tilting interact in the cubic phase CsBBr₃, with B = Pb, Sn, and Ge. We find that lone pair-induced off-centering and octahedral tilting are symmetry-decoupled. Instead, stereochemical lone pair expression of the B-site ion is correlated to octahedral tilting through the propensity of the B-site to form a transient, partial covalent bond with the surrounding halide ions that stiffens octahedral tilting modes. These results link local electronic asymmetry to structural fluctuations and suggest that dynamic modulation of electronic symmetry offers a pathway to control functional properties in halide perovskites.