⌘+K

Pulse Explore Communities Researchers Journals

Home Communities Explore

January 1, 2026Organic Chemistry FrontiersOpen Access

Enantioselective BIMP-catalysed [2,3]-Wittig Rearrangements of Oxindole-Derived Allylic and Propargylic Ethers

Órla Conboy Justin O’Yang Kevin Kasten David B. Cordes Aidan P. McKay Tengfei Kang Andrew D. Smith

View Full Paper

Ask AI

Bookmark

Share

Key Points

This research investigates the use of organocatalytic methods to achieve enantioselective rearrangements of oxindole-derived ethers.
Utilized bifunctional iminophosphorane (BIMP) as organocatalysts.
Conducted [2,3]-Wittig rearrangements on various allylic and propargylic ethers.
Analyzed the stereochemical outcomes of the reactions.
Achieved high stereoselectivity in the synthesis of 3-hydroxyoxindole derivatives.
Generated a range of oxindole derivatives through the proposed methodology.

No abstract yet

We only have this paper's title and publication details.

Read it at the source→

Implication

Enantioselective reactions generate diverse oxindole derivatives, indicating advances in organic synthesis techniques.

Discussion

No takes yet. Share an insight, caveat, or question.

Cite This Study

Conboy et al. (2026) studied this question.

synapsesocial.com/papers/69c4cd05fdc3bde448918d69 https://doi.org/10.1039/d6qo00342g

View Full Paper

Ask AI

Bookmark

Share

Keep reading

Synapse has enriched 5 closely related papers on similar clinical questions. Consider them for comparative context:

1Chemoselectivity Switch between Enantioselective [2,3]‐Wittig Rearrangement and Conia‐Ene‐Type Reactions of Propargyloxyoxindoles2024 · 1 citations
2Catalytic Enantioselective Dearomatizing [2,3]-Wittig Rearrangements Allow Divergent [2,3]-, [1,2]-, and Sommelet–Hauser-Type ProductsOriginal Research · 2026
3Enantioselective [2,3]-Wittig rearrangement of allyl picolyl ethers with chiral lithium amides2025 · 2 citations
4Organocatalytic Highly Enantioselective Formal [1,3] Sigmatropic Rearrangement of Indole Alkyl Ethers and Mechanistic Insight2024 · 8 citations
5Organocatalytic Enantioselective Dearomatization of 2,3‐Disubstituted Indoles with <i>α</i> ‐(3‐Indolyl)propargylic Alcohols2025