Enantioselective rearrangement produces 1-(2-pyridyl)-3-butenol from allyl ethers, suggesting impact in synthetic chemistry.
Highly enantioselective [2,3]-Wittig rearrangement of 2-(allyloxymethyl)pyridine using chiral lithium amides to give 1-(2-pyridyl)-3-butenol with up to 95% ee was achieved.
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Kawasaki et al. (2025) studied this question.
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