Demonstrates improved hydrogen evolution in photoelectrochemical cells with Zn-doped quantum dots, indicating significant stability advancements.
The photo-corrosion of sulfide quantum dots (QDs) always limits the applications in photoelectrochemical (PEC) cells as photo-sensitizers. Herein, Zn-doped CuFeS₂(ZCIS) QDs were synthesized to sensitize TiO₂/F-doped Tin oxide (FTO) glass photoanode. After Zn introduction, S₂²⁻ existed in CuFeS₂(CIS) QDs with high chemical activity disappears and the average grain size of Zn:CuFeS₂ reduces, enhancing the quantum confinement effect that accelerates the separation and transfer of photogenerated carriers. After coated with ZnS passivation layer, ZnS/ZCIS/TiO₂/FTO photoanode was employed for H₂ evolution, constituting Pt sheet electrode in aqueous electrolyte. The I-type ZnS/ZCIS heterojunction not only suppresses back electron transfer, but also promotes transfer of carriers furtherly. Zn doping and ZnS coating inhibit photo-corrosion of ZCIS QDs, and improve PEC performance and stability significantly. Under one sun illumination (100 mW/cm²), ZnS/ZCIS/TiO₂/FTO photoanode based cell has achieved accumulative H₂yield 642.17 μmol/cm² for 4 h with average rate 160.54 μmol/cm²/h at 0.6 V bias. After 16-hour H₂ evolution in 4-cycle test, the average rate decreases only 2.13%.
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Lian et al. (2026) studied this question.
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