Accessing quasiflat f bands to harvest large Berry curvature in NdGaSi

In typical rare-earth lanthanide compounds, the localized $4f$ electrons have a weak effect on the electrical conduction, limiting their influence on the Berry curvature and, hence, the intrinsic anomalous Hall effect. A comprehensive study of the magnetic, thermodynamic, and transport properties of single-crystalline NdGaSi, guided by first1000-0ptprinciples calculations, reveals a ferromagnetic ground state that induces a splitting of quasiflat $4f$ electronic bands and positions them near the Fermi energy. The observation of an extraordinarily large intrinsic anomalous Hall conductivity of 11650.16em0exΩ^-10.16em0excm^-1 implies the direct involvement of localized states in the generation of nontrivial band crossings around the Fermi energy. The angle-resolved photoemission spectroscopy measurements provide direct evidence of nontrivial crossing of the $4f$ bands with dispersive bands. These results are remarkable when compared to ferrimagnetic NdAlSi, which differs only in a nonmagnetic atom (a change in the principal quantum number n of the outer p orbital) with the same number of valence electrons and does not exhibit any measurable anomalous Hall conductivity.