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March 28, 2026Chemistry & Biodiversity

Biodegradable Poly(Vinyl Alcohol)/Starch Films Crosslinked With Itaconic Acid for Sustainable Packaging Applications

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Authors

AIAsylzat IskalievaBLBekbayeva LyazzatKAKhaldun M. Al Azzam

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Overview

Biodegradable films improve mechanical performance in sustainable packaging, indicating promising alternatives to plastics.

Key Points

  • This research investigates the properties of biodegradable films made from poly(vinyl alcohol), starch, and itaconic acid for sustainable packaging applications.
  • Fabrication of films via solution casting using various ratios of PVA, starch, and itaconic acid.
  • Characterization using FTIR to confirm crosslinking.
  • Mechanical testing for tensile strength and elongation measurement.
  • Viscosity and decomposition temperature assessments.
  • Biodegradation analysis in soil over 30 days.
  • The balanced PVA/S/IA film exhibited the highest tensile strength of 10.5 ± 0.8 MPa and elongation at break of 38.9% ± 2.4%.
  • IA-rich films showed increased viscosity up to 3250 ± 110 cP and improved thermal stability by 15°C-20°C compared to starch-rich films.
  • Starch-rich films had a faster biodegradation rate, with a mass loss of 67% in 30 days versus 42% for balanced films and 28% for IA-rich films.
  • All films fragmented in water within 24 hours due to a crosslinked network.

Cite This Study

Iskalieva et al. (2026) studied this question.

synapsesocial.com/papers/69c7722a8bbfbc51511e2675https://doi.org/10.1002/cbdv.202503824
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