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January 1, 2025Координационная химия / Russian Journal of Coordination Chemistry

Alkaline Earth Metal Bisamides Based on Unsymmetrical Acenaphthene-1,2-diimine

A.A. Bazanov A.A. Skatova E.V. Baranov I.L. Fedushkin

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Key Points

The research aims to synthesize and characterize alkaline earth metal bisamides from a specific diimine compound.
Reduction of diimine with magnesium, calcium, strontium, or barium.
Use of catalytic amounts of corresponding iodides.
Characterization via IR and NMR spectroscopy, elemental analysis, and single crystal X-ray analysis.
Formation of complexes [(Ar-bian)Mg(Thf)(Dme)], [(Ar-bian)Ca(Dme)], [(Ar-bian)Sr(Dme)], and [(Ar-bian)Ba(Dme)].
Successful characterization of compounds through multiple analytical techniques.

Implication

Synthesizes alkaline earth metal complexes in organic chemistry, suggesting potential applications in material science.

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Cite This Study

Bazanov et al. (2025) studied this question.

synapsesocial.com/papers/69c8c336de0f0f753b39ddae https://doi.org/10.7868/s3034549925110015

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