PdNeuRAM: forming-free, multi-bit Pd/HfO2 ReRAM for energy-efficient neuromorphic computing

Memristor technology offers a promising route toward energy-efficient computing but faces challenges including resistance drift, variability, and the need for electroforming. Filamentary resistive random-access memory, one of the most studied memristive platforms, typically requires a high-voltage electroforming step to initiate conductive filaments, leading to increased power overhead and reduced endurance. Here we report HfO2-based forming-free memristive devices (PdNeuRAM) that operate at low voltages, support multi-bit functionality, and exhibit reduced variability. Through combined electrical and materials characterization, we identify a Pd-O-Hf interfacial configuration that lowers oxygen-vacancy formation and migration barriers, creating a dense network of shallow defect states. Together with a Ti top electrode acting as an oxygen reservoir and an ultrathin (5 nm) HfO2 layer, this interfacial engineering enables charge redistribution at room temperature and eliminates the need for electroforming. The fabricated devices provide tunable resistance states and reduce programming and read energy by 43% and 38%, respectively, in spiking neural network inference tasks. These results provide mechanistic insight into forming-free resistive switching and demonstrate the potential of Pd/HfO2 devices for energy-efficient neuromorphic computing. Resistive memory devices often require an energy-intensive forming step that limits efficiency and reliability. Erbing Hua and colleagues report forming-free Pd/HfO2 devices enabled by a Pd-O-Hf interfacial mechanism, supporting multi-bit operation and reduced energy use in spiking neural networks.