Reveals how chlorine pressure affects electromotive force in silver/chloride cells, suggesting key insights into electrode behavior.
The influence of chlorine pressure on potentials of silver/silver chloride electrode have been studied for the cells of Ag/AgCI/Cl2PmmHg (C) and of Ag/AgCI･KCI (70 : 30 mol. )/Cl2PmmHg (C) below one atm. at 500℃ and 600℃. The e.m.f. did scarecely depend on a half power of chlorine pressures below one atm. Coresponding to the color chang of a melt three kinds of pressure dependency were essentially found for both salts. The relation between the e.m.f. and the pressure was generally explained by introduction of cation vacancies and anion vacancies in these melts.
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ISEKI et al. (1968) studied this question.
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