Effects of Pd Addition on the Electrochemical Properties of MgNi

Two groups of Pd-modified MgNi samples were prepared: sample Ⅰ, ball-milling Pd (1, 6 and 10 mol%) with amorphous MgNi for 10 min, 2hr or 10 hr, sample Ⅱ, ball-milling 10 mol% Pd with Mg2Ni and Ni for 80 hr. Effects of the addition of Pd on the electrochemical properties of MgNi were investigated. For sample Ⅰ, the effects of Pd depended on both the Pd ratio and the time of ball-milling. During ball-milling, Pd bebame amorphous and was distributed uniformly on the surface of MgNi particle. At 6 mol% and 10 mol% Pd, degradation of the discharge capacity of MgNi was significantly decreased. As for sample Ⅱ, the cycle life of MgNi was remarkably improved by Pd modification. The roles of Pd in the behavior of MgNi were analyzed, and the improvements in MgNi properties arising from both modifications by Pd were thought to be due to the prevention of the formation of Mg(OH)2.