Synthesis of Macro-rotaxanes via Direct Trapping of Multicyclic Poly(n-butyl acrylate) in a Cross-linked Network

Kotaro Ibe; Yamato Ebii; Minami Ebe; Kazushige Suzuki; Takayuki Kurokawa; Takuya Yamamoto; Feng Li; Takuya Isono; Toshifumi Satoh

doi:10.1039/d6py00144k

January 1, 2026Polymer Chemistry

Synthesis of Macro-rotaxanes via Direct Trapping of Multicyclic Poly(n-butyl acrylate) in a Cross-linked Network

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Key Points

The aim is to explore the synthesis of macro-rotaxanes and their applications in materials.
Direct trapping of multicyclic poly(n-butyl acrylate) in a cross-linked network was employed for synthesis.
Synthesis processes were optimized to overcome previous synthetic challenges.
Successfully synthesized macro-rotaxanes with both linear and cyclic polymer components.
Showed that these macro-rotaxanes have unique structural characteristics that may enhance material properties.

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Implication

This research demonstrates the synthesis of macro-rotaxanes, highlighting their potential applications in material science.

Abstract

Macro-rotaxanes, in which both the linear and cyclic components are polymers, remain largely unexplored in terms of their formation and potential material applications due to the synthetic challenges associated with...

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Ibe et al. (2026) studied this question.

synapsesocial.com/papers/69cd7b575652765b073a93b7 https://doi.org/10.1039/d6py00144k

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Synthesis of Macro-rotaxanes via Direct Trapping of Multicyclic Poly(n-butyl acrylate) in a Cross-linked Network

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

Synthesis of Macro-rotaxanes via Direct Trapping of Multicyclic Poly(n-butyl acrylate) in a Cross-linked Network

Key Points

Ask about this paper

Implication

Abstract

Discussion

Cite This Study

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