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January 1, 2025RSC AdvancesOpen Access

Rotaxane synthesis via a dynamic [2]catenane-ring-opening, axle-cleaving double cross metathesis

M. Mustafa Çetin Arindam Mazumdar Vahap Gazi Fidan

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Key Points

Dynamic synthesis enhances efficiency in creating rotaxanes, minimizing byproduct formation.
The method implements double cross metathesis to streamline formation of interlocked structures.
Employing innovative strategies reduces the issues associated with non-recoverable byproducts.
This advancement highlights potential improvements in synthetic chemistry techniques.],

Implication

Dynamic approach improves synthesis of rotaxanes, suggesting reduced non-interlocked byproducts.

Abstract

Efficient routes to [2]rotaxanes are often compromised by formation of irrecoverable, non-interlocked byproducts.

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Cite This Study

Çetin et al. (2025) studied this question.

synapsesocial.com/papers/6930dc81ea1aef094cca25b9 https://doi.org/10.1039/d5ra07142a

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