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September 14, 2025

Reversible Mechanical Interlocking via Stimuli-Triggered Nonhomeomorphic Topology Transformation Enables Highly Efficient Rotaxane Synthesis.

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Authors

CXChun-Lin XiaoGannan Medical UniversityXLXue LiThe University of OsakaNONaotaka OkamotoOsaka Rosai Hospital

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Implication

This method demonstrates high conversion rates in rotaxane synthesis, suggesting advances in reversible topology transformation.

Key Points

  • The method achieves over 99% conversion for [2]rotaxane, with notable yields.
  • Rotaxanes with distinct geometries are synthesized using UV light, showcasing innovative reversible techniques.
  • Heat-triggered transformations allow mechanical unlocking without additional reagents, emphasizing efficiency.
  • The approach highlights the thermal stability of certain rotaxanes, indicating potential applications in advanced materials.

Cite This Study

Xiao et al. (2025) studied this question.

synapsesocial.com/papers/68c6df6de03a6c7bdc170fd5https://doi.org/10.1002/anie.202513783
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