ABSTRACT Conventional SF 6 based etching in HBM packaging faces low yield and edge breakage due to poor profile control and high GWP. To address this, a multi‐step strategy using ClF 3 , IF 7 , and C 4 F 6 is proposed. While ClF 3 enables efficient thinning, a combination of ClF 3 /IF 7 /C 4 F 6 with a localized magnetic field precisely modulates the wafer edge profile. Plasma diagnostics show that IF 7 induces electron scavenging, reducing plasma reactivity via iodine species to prevent over‐etching at the periphery. This approach ensures high yield, minimal surface damage, and tailored silicon profiles. Ultimately, this low‐GWP chemistry provides a high‐performance, sustainable alternative to SF 6 , meeting the stringent mechanical and environmental requirements for next‐generation HBM integration.
Hong et al. (Wed,) studied this question.