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This work presents the synthesis and intriguing photoluminescence of the Au₄₂(PET)₃₂ (PET = 2-phenylethanethiolate) nanocluster (NC). The Au₄₂(PET)₃₂ NC exhibits dual emission at 875 and 1040 nm, which are revealed to be fluorescence and phosphorescence, respectively. The emission quantum yield (QY) of Au₄₂(PET)₃₂ in dichloromethane is 11.9% at room temperature in air, which is quite rare for thiolate-protected Au NCs. When Au₄₂(PET)₃₂ NCs are embedded in polystyrene films (solid state), the fluorescence was dramatically suppressed while the phosphorescence was significantly enhanced. This divergent behavior is explained by dipolar interaction-induced enhancement of intersystem crossing from singlet to triplet excited state.
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Luo et al. (2022) studied this question.
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