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November 12, 2014Chemical Reviews

Research Development on Sodium-Ion Batteries

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Authors

NYNaoaki YabuuchiYokohama National UniversityKKKei KubotaNational Institute for Materials ScienceMDMouad DahbiUniversité Mohammed VI Polytechnique

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Implication

Comprehensive review demonstrates progress in electrode materials and electrolytes for sodium-ion cells, highlighting viable low-cost alternatives to lithium technology.

Key Points

  • Summarize scientific progress, operating mechanisms, and chemical challenges in the development of rechargeable sodium-ion batteries as sustainable alternatives to lithium-ion systems.
  • Comprehensive literature review surveying crystal chemistry, synthesis methods, and electrochemical performance of sodium insertion materials.
  • Systematic comparison of positive electrode materials, negative electrode materials, and compatible nonaqueous electrolyte solutions.
  • Layered transition metal oxides, polyanionic frameworks, and Prussian blue analogs demonstrate reversible sodium intercalation with distinct operating voltages and phase transitions.
  • Hard carbon and intermetallic alloying materials provide functional storage capacity as negative electrodes despite larger ionic radius constraints relative to lithium.
  • Electrolyte optimization and protective interface formation are identified as primary determinants of Coulombic efficiency and long-term cycling stability.

Cite This Study

Yabuuchi et al. (2014) studied this question.

synapsesocial.com/papers/69d71b66236f4746d45637ebhttps://doi.org/10.1021/cr500192f
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