Advances in Charge Carrier Mobilities of Semiconducting Polymers Used in Organic Transistors

In this review, we describe and discuss recent advances in the performance of polymeric semiconductors in organic field effect transistors (OFETs). Design concepts such as short intermolecular contacts, low conformational disorder, side chain optimization, and noncovalent interactions have all been successfully employed to improve the charge carrier mobility of polymer thin films. The relationship between the molecular design, thin film microstructure, and electrical performance has been exemplified by a range of thiophene, bridged and fused ring, diketopyrrolopyrrole (DPP), and isoindigo containing polymers which are reviewed and discussed.