Recent Progress of Electrochemical Production of Hydrogen Peroxide by Two‐Electron Oxygen Reduction Reaction

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Shifting electrochemical oxygen reduction reaction (ORR) via two-electron pathway becomes increasingly crucial as an alternative/green method for hydrogen peroxide (H₂ O₂ ) generation. Here, the development of 2e⁻ ORR catalysts in recent years is reviewed, in aspects of reaction mechanism exploration, types of high-performance catalysts, factors to influence catalytic performance, and potential applications of 2e⁻ ORR. Based on the previous theoretical and experimental studies, the underlying 2e⁻ ORR catalytic mechanism is firstly unveiled, in aspect of reaction pathway, thermodynamic free energy diagram, limiting potential, and volcano plots. Then, various types of efficient catalysts for producing H₂ O₂ via 2e⁻ ORR pathway are summarized. Additionally, the catalytic active sites and factors to influence catalysts' performance, such as electronic structure, carbon defect, functional groups (O, N, B, S, F etc.), synergistic effect, and others (pH, pore structure, steric hindrance effect, etc.) are discussed. The H₂ O₂ electrogeneration via 2e⁻ ORR also has various potential applications in wastewater treatment, disinfection, organics degradation, and energy storage. Finally, potential future directions and prospects in 2e⁻ ORR catalysts for electrochemically producing H₂ O₂ are examined. These insights may help develop highly active/selective 2e⁻ ORR catalysts and shape the potential application of this electrochemical H₂ O₂ producing method.