Z‐Scheme Photocatalytic Systems for Carbon Dioxide Reduction: Where Are We Now?

Transforming CO₂ into fuels by utilizing sunlight is promising to synchronously overcome global warming and energy-supply issues. It is crucial to design efficient photocatalysts with intriguing features such as robust light-harvesting ability, strong redox potential, high charge-separation, and excellent durability. Hitherto, a single-component photocatalyst is incapable to simultaneously meet all these criteria. Inspired by natural photosynthesis, constructing artificial Z-scheme photocatalysts provides a facile way to conquer these bottlenecks. In this review, we firstly introduce the fundamentals of photocatalytic CO₂ reduction and Z-scheme systems. Thereafter we discuss state-of-the-art Z-scheme photocatalytic CO₂ reduction, whereby special attention is placed on the predominant factors that affect photoactivity. Additionally, further modifications that are important for efficient photocatalysis are reviewed.