Bakerian Lecture :—Rays of positive electricity

Abstract In 1886, Goldstein observed that when the cathode in a vacuum tube was pierced with holes, the electrical discharge did not stop at the cathode; behind the cathode, beams of light could be seen streaming through the holes in the way represented in fig. 1. He ascribed these pencils of light to rays passing through the holes into the gas behind the cathode; and from their association with the channels through the cathode he called these rays Kanalstrahlen. The colour of the light behind the cathode depends upon the gas in the tube: with air the light is yellowish, with hydrogen rose colour, with neon the gorgeous neon red, the effects with this gas being exceedingly striking. The rays produce phosphorescence when they strike against the walls of the tube; they also affect a photographic plate. Goldstein could not detect any deflection when a permanent magnet was held near the rays. In 1898, however, W. Wien, by the use of very powerful magnetic fields, deflected these rays and showed that some of them were positively charged; by measuring the electric and magnetic deflections he proved that the masses of the particles in these rays were comparable with the masses of atoms of hydrogen, and thus were more than a thousand times the mass of a particle in the cathode ray. The composition of these positive rays is much more complex than that of the cathode rays, for whereas the particles in the cathode rays are all of the same kind, there are in the positive rays many different kinds of particles. We can, however, by the following method sort these particles out, determine what kind of particles are present, and the velocities with which they are moving. Suppose that a pencil of these rays is moving parallel to the axis of x, striking a plane at right angles to their path at the point O; if before they reach the plane they are acted on by an electric force parallel to the axis of y, the spot where a particle strikes the plane will be deflected parallel to y through a distance y given by the equation y = e/mv2 A, where e, m, v, are respectively the charge, mass, and velocity of the particle, and A a constant depending upon the strength of the electric field and the length of path of the particle, but quite independent of e, m, or v.