The thermal dissociation of COS was investigated in shock waves with argon as carrier gas. The concentration was varied between 0.05 and 0.5% COS in argon, the total density from 2.5 × 10 −5 mole/cm 3 to 2.5 × 10 −3 mole/cm 3 . Temperatures between 1500°K and 3100°K were applied. For the reaction the rate constant was found to be in the low pressure range of the unimolecular reaction and in the high pressure range.
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Schecker et al. (1969) studied this question.
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