Wide‐coverage and Efficient NIR Emission from Single‐component Nanophosphors through Shaping Multiple Metal‐halide Packages

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Wide-coverage near infrared (NIR) phosphor-converted LEDs possess promising potential for practical applications, but little is developed towards the efficient and wide-coverage NIR phosphors. Here, we report the single-component lanthanide (Ln³⁺ ) ions doped Cs₂ M(In0.95 Sb0.05 )Cl₆ (M=alkali metal) nanocrystals (NCs), exhibiting emission from 850 to 1650 nm with high photoluminescence quantum yield of 20.3 %, which is accomplished by shaping the multiple metal halide octahedra of double perovskite via the simple alkali metal substitution. From Judd-Ofelt theoretical calculation and spectroscopic investigations, the shaping of metal halide octahedra in Cs₂ M(In1-x Sbx )Cl₆ NCs can break the forbidden of f-f transition of Ln³⁺ , thus increasing their radiative transition rates and simultaneously boosting the energy transfer efficiency from host to Ln³⁺ . Finally, the wide-coverage NIR LEDs based on Sm³⁺ , Nd³⁺ , Er³⁺ -tridoped Cs₂ K0.5 Rb0.5 (In0.95 Sb0.05 )Cl₆ NCs are fabricated and employed in the multiplex gas sensing and night-vision application.