January 1, 1998

Gold(I) complexes with amine ligands. 3 Competition between auriophilic and hydrogen bonding interactions in dimeric species

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Resumen

The gold(I) complexes (pip)2Au+Cl- and (Cy2NH)AuCl (pip=piperidine, Cy=cyclohexyl) crystallise as loose dimers; in the ionic species N–H···Cl- hydrogen bonding is the main secondary interaction, whereas in the neutral complex the N–H···Cl hydrogen bonding is weaker but is compensated by an auriophilic interaction.

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Jones et al. (Thu,) studied this question.

synapsesocial.com/papers/69d963ab00ab073a27836573 https://doi.org/https://doi.org/10.1039/a805587d

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