Unveiling the Effects of Hydrolysis‐Derived DMAI/DMAPbIx Intermediate Compound on the Performance of CsPbI₃ Solar Cells

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Introducing hydroiodic acid (HI) as a hydrolysis-derived precursor of the intermediate compounds has become an increasingly important issue for fabricating high quality and stable CsPbI₃ perovskite solar cells (PSCs). However, the materials composition of the intermediate compounds and their effects on the device performance remain unclear. Here, a series of high-quality intermediate compounds are prepared and it is shown that they consist of DMAI/DMAPbI x . Further characterization of the products show that the main component of this system is still CsPbI₃. Most of the dimethylammonium (DMA⁺) organic component is lost during annealing. Only an ultrasmall amount of DMA⁺ is doped into the CsPbI₃ and its structure is stabilized. Meanwhile, excessive DMA⁺ forms Lewis acid-base adducts and interactions with Pb²⁺ on the CsPbI₃ surface. This process passivates the CsPbI₃ film and decreases the recombination rate. Finally, CsPbI₃ film is fabricated with high crystalline, uniform morphology, and excellent stability. Its corresponding PSC exhibits stable property and improved power conversion efficiency (PCE) up to 17.3%.