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The kinetics of simultaneous, noncatalytic solid‐gas reaction systems has been analyzed in terms of the selectivity and effectiveness factor, based on the unreacted core shrinking model. The reaction systems discussed include the first‐order independent, parallel, and consecutive reactions with the simultaneous influences of heat and mass transfer. The effects of various chemical and transport properties on the stability, selectivity, and effectiveness factor of the system are discussed. The pseudosteady state approximation is employed to reduce the mathematical difficulties.
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Wen et al. (1971) studied this question.
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