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This research develops a photocatalyst-free method that enhances ynamide formation from carbamoyl radicals, suggesting a new synthetic approach.
A photocatalyst-free, visible-light-enabled alkynylation of carbamoyl radicals has been developed, facilitating streamlined access to alkynyl amides (ynamides). We use readily prepared carbamoyl-functionalized dihydroquinazolinone precursors, which undergo aromatization-driven C-C bond cleavage...
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Jia et al. (2026) studied this question.
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