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April 11, 2026Inorganic Chemistry Frontiers1 citationsOpen Access

Spin-Crossover Tuning in Synergistic Luminescent Fe(II) Coordination Compounds via Topochemical 4+4 Photocycloaddition of an Anthracene-Based Ligand

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MSMatthias SchöbingerMHMartin HuberSMSophia Mundigler

Key Points

  • This research aims to explore the relationship between spin crossover and luminescence in coordination polymers.
  • Synthesis of coordination polymers incorporating an anthracene-based ligand
  • Topochemical [4+4] photocycloaddition process applied for ligand modification
  • Assessment of photoluminescent properties in synthesized compounds
  • Successful creation of coordination polymers that exhibit spin crossover phenomena
  • Enhanced photoluminescent properties observed in specific compounds
  • Identified potential applications in optical sensing of spin states

Abstract

Coordination polymers (CPs) designed to couple spin crossover (SCO) and photoluminescence (PL) properties hold significant potential for sensor applications, enabling optical readout of spin states. We report the synthesis of...

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Cite This Study

Schöbinger et al. (2026) studied this question.

synapsesocial.com/papers/69d9e67a78050d08c1b76db5https://doi.org/10.1039/d5qi01281c
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