Advances and Challenges for the Electrochemical Reduction of CO₂ to CO: From Fundamentals to Industrialization

The electrochemical carbon dioxide reduction reaction (CO₂ RR) provides an attractive approach to convert renewable electricity into fuels and feedstocks in the form of chemical bonds. Among the different CO₂ RR pathways, the conversion of CO₂ into CO is considered one of the most promising candidate reactions because of its high technological and economic feasibility. Integrating catalyst and electrolyte design with an understanding of the catalytic mechanism will yield scientific insights and promote this technology towards industrial implementation. Herein, we give an overview of recent advances and challenges for the selective conversion of CO₂ into CO. Multidimensional catalyst and electrolyte engineering for the CO₂ RR are also summarized. Furthermore, recent studies on the large-scale production of CO are highlighted to facilitate industrialization of the electrochemical reduction of CO₂ . To conclude, the remaining technological challenges and future directions for the industrial application of the CO₂ RR to generate CO are highlighted.