Surface Activation and Ni‐S Stabilization in NiO/NiS₂for Efficient Oxygen Evolution Reaction

Manipulating the active species and improving the structural stabilization of sulfur-containing catalysts during the OER process remain a tremendous challenge. Herein, we constructed NiO/NiS₂ and Fe-NiO/NiS₂ as catalyst models to study the effect of Fe doping. As expected, Fe-NiO/NiS₂ exhibits a low overpotential of 270 mV at 10 mA cm⁻² . The accumulation of hydroxyl groups on the surface of materials after Fe doping can promote the formation of highly active NiOOH at a lower OER potential. Moreover, we investigated the level of corrosion of M-S bonds and compared the stability variation of M-S bonds with Fe at different locations. Interestingly, Fe bonded with S in the bulk as the sacrificial agent can alleviate the oxidation corrosion of partial Ni-S bonds and thus endow Fe-NiO/NiS₂ long-term durability. This work could motivate the community to focus more on resolving the corrosion of sulfur-containing materials.