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February 13, 2020ACS Energy Letters

An Empirical Model for the Design of Batteries with High Energy Density

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Authors

YWYingqiang WuHainan UniversityLXLeqiong XieHainan UniversityHMHai MingInternational College of Defence Studies

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Overview

Computational modeling reveals critical multiparameter constraints for reaching over 300 Wh kg–1 in rechargeable batteries, indicating that electrode capacity alone is insufficient for cell design.

Key Points

  • To formulate an empirical model incorporating multiple cell design parameters to accurately predict pathways for achieving battery energy densities exceeding 300 Wh kg–1.
  • Developed an empirical battery model integrating electrode capacities alongside areal loading density, operating voltage difference, anode-to-cathode initial capacity balance, and initial Coulombic efficiency.
  • Applied the multivariable framework to analyze current battery configurations and identify target parameter combinations capable of exceeding 300 Wh kg–1.
  • Demonstrated that high lithium storage capacity in electrode materials is insufficient on its own to achieve target cell energy densities without optimizing other design parameters.
  • Identified that multiparameter co-optimization of areal loading, voltage difference, capacity balance, and initial Coulombic efficiency can successfully yield battery designs delivering >300 Wh kg–1.

Cite This Study

Wu et al. (2020) studied this question.

synapsesocial.com/papers/69daab87a6045d71bfa3db61https://doi.org/10.1021/acsenergylett.0c00211
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