Anode Materials for Aqueous Zinc Ion Batteries: Mechanisms, Properties, and Perspectives

Aqueous Zn-ion batteries (ZIBs) are promising safe energy storage systems that have received considerable attention in recent years. Based on the electrochemical behavior of Zn²⁺ in the charging and discharging process, herein we review the research progress on anode materials for use in aqueous ZIBs based on two aspects: Zn deposition and Zn²⁺ intercalation. To date, Zn dendrite, corrosion, and passivation issues have restricted the development of aqueous ZIBs. However, many strategies have been developed, including structural design, interface protection of the Zn anode, Zn alloying, and using polymer electrolytes. The main aim is to stabilize the Zn stripping/plating layer and limit side reactions. Zn²⁺-intercalated anodes, with a high Zn²⁺ storage capacity to replace the current metal Zn anode, are also a potential option. Finally, some suggestions have been put forward for the subsequent optimization strategy, which are expected to promote further development of aqueous ZIBs.