Palladium and fluoroalkyl radical catalysis enables C7-H functionalization of indoles, suggesting efficient synthesis of lilolidines.
Herein, we report a cooperative palladium and fluoroalkyl radical catalysis strategy that enables the direct C7-H functionalization/annulation of unactivated olefin-tethered N-alkyl indoles with bromofluoroalkyl reagents. This method provides efficient access...
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Zhao et al. (2026) studied this question.
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