What question did this study set out to answer?

To establish an accurate X-ray photoelectron spectroscopy method for quantifying mixed nickel metal, oxide, hydroxide, and oxyhydroxide states and detecting low levels of Ni(III) species.

January 28, 2009Surface and Interface AnalysisOpen Access

X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems

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To establish an accurate X-ray photoelectron spectroscopy method for quantifying mixed nickel metal, oxide, hydroxide, and oxyhydroxide states and detecting low levels of Ni(III) species.
Acquired reference standard spectra for Ni, NiO, Ni(OH)2, and NiOOH to enable systematic spectral subtraction.
Combined data analysis of Ni 2p and O 1s core-level spectra to evaluate commercial nickel powder and a thin nickel oxide film grown at 1-Torr O2 and 300 °C for 20 minutes.
Assessed analysis depth using calculated inelastic mean free paths and examined relative sensitivity factor uncertainties (Ni 2.67 ± 0.54).
Successfully demonstrated qualitative detection of low concentrations of Ni(III) and quantitative separation of mixed oxidation states via reference spectral subtraction.
Validated chemical state quantification across commercial nickel powder and thin oxide films while detailing the impact of sensitivity factor variance (2.67 ± 0.54).

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Implication

Experimental study demonstrates chemical state quantification in mixed nickel systems, highlighting spectral subtraction protocols for complex surface analysis.

Cite This Study

Biesinger et al. (2009) studied this question.

synapsesocial.com/papers/69dc353dd74bf23813c0fb12 https://doi.org/10.1002/sia.3026

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Implication

Experimental study demonstrates chemical state quantification in mixed nickel systems, highlighting spectral subtraction protocols for complex surface analysis.

X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems

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Discussion

Implication

Cite This Study

X‐ray photoelectron spectroscopic chemical state quantification of mixed nickel metal, oxide and hydroxide systems

Key Points

Discussion

Implication

Cite This Study

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