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May 14, 2011Science6,144 citations

Carbon-Based Supercapacitors Produced by Activation of Graphene

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YZYanwu ZhuSMShanthi MuraliMSMeryl D. Stoller

Key Points

  • The aim is to develop high-performance carbon-based supercapacitors by enhancing material properties.
  • Synthesis of porous carbon through chemical activation of exfoliated graphite oxide.
  • Assessment of surface area (up to 3100 m²/g) and electrical conductivity.
  • Construction of two-electrode supercapacitor cells with organic and ionic liquid electrolytes.
  • Achieved high gravimetric capacitance and energy density with low oxygen and hydrogen content.
  • Demonstrated scalability of carbon production processes for industrial applications.

Abstract

Supercapacitors, also called ultracapacitors or electrochemical capacitors, store electrical charge on high-surface-area conducting materials. Their widespread use is limited by their low energy storage density and relatively high effective series resistance. Using chemical activation of exfoliated graphite oxide, we synthesized a porous carbon with a Brunauer-Emmett-Teller surface area of up to 3100 square meters per gram, a high electrical conductivity, and a low oxygen and hydrogen content. This sp(2)-bonded carbon has a continuous three-dimensional network of highly curved, atom-thick walls that form primarily 0.6- to 5-nanometer-width pores. Two-electrode supercapacitor cells constructed with this carbon yielded high values of gravimetric capacitance and energy density with organic and ionic liquid electrolytes. The processes used to make this carbon are readily scalable to industrial levels.

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Cite This Study

Zhu et al. (2011) studied this question.

synapsesocial.com/papers/69dc897c34612599f3359296https://doi.org/10.1126/science.1200770
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