Humidity-Responsive Photonic Crystals with pH and SO₂ Gas Detection Ability Based on Cholesteric Liquid Crystalline Networks

Dynamic photonic crystals with tunable structural colors have been a hot topic in the research of anticounterfeiting devices, decoration, and detection. In this work, we prepared cholesteric liquid crystalline network (CLCN)-based photonic crystals that present humidity- and SO₂ gas-responsive behaviors. The covalently cross-linked CLCN film presents humidity-responsive color changes due to the swelling/deswelling of the matrix under different humidity conditions. When treating the CLCN film with SO₂ gas, the carboxylic salt converted to the acid and the film was not able to respond to the humidity change anymore. The mechanism of the SO₂ gas-gated humidity responsiveness of the CLCN film was characterized. It was found that the acidic gas caused changes of pH, resulting in the conversion of the salt to acid and alteration of the surface property. The influence of concentration of SO₂ gas and pH on humidity responsiveness of the CLCN film was investigated. We hope that this method provides inspirations for the design and fabrication of visualized pH and acidic gas detectors.