Starting from a readily available fluoral derivative, catalytic aromatic trifluoromethylation has been successfully achieved. A small amount of copper(I) iodide‐phenanthroline complex catalyzed the cross‐coupling reactions of aryl/heteroaryl iodides with the O ‐silylated hemiaminal of fluoral (trifluoroacetaldehyde) to provide trifluoromethylated arenes in moderate to high yields.
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Kondo et al. (2011) studied this question.
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