What question did this study set out to answer?

Synthesize flexible, dynamic coordination polymers and investigate their structural transformation upon the adsorption of supercritical gases.

January 27, 2003Angewandte Chemie International Edition

Porous Coordination‐Polymer Crystals with Gated Channels Specific for Supercritical Gases

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Authors

RKRyo KitauraHokkaido University KSKenji SekiTenri Hospital GAGeorge AkiyamaKanazawa University

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Implication

Materials study demonstrates reversible crystal transformation and gas adsorption in flexible coordination polymers, highlighting adaptive porous materials for gas capture.

Key Points

Synthesize flexible, dynamic coordination polymers and investigate their structural transformation upon the adsorption of supercritical gases.
Synthesized flexible coordination polymers utilizing interpenetrated and interdigitated structural frameworks.
Characterized reversible phase transitions and surface area changes during gas adsorption testing.
Induced reversible crystal-to-crystal transformations triggered specifically by the adsorption of various supercritical gases.
Expanded specific surface area from a nonporous state of 24 m² g⁻¹ to a microporous state of at least 320 m² g⁻¹.

Cite This Study

Kitaura et al. (2003) studied this question.

synapsesocial.com/papers/69dd59df80eea7d3f699bc5b https://doi.org/10.1002/anie.200390130

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Implication

Materials study demonstrates reversible crystal transformation and gas adsorption in flexible coordination polymers, highlighting adaptive porous materials for gas capture.

Porous Coordination‐Polymer Crystals with Gated Channels Specific for Supercritical Gases

Discussion

Member takes

Implication

Key Points

Cite This Study

Porous Coordination‐Polymer Crystals with Gated Channels Specific for Supercritical Gases

Discussion

Member takes

Implication

Key Points

Cite This Study

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