A Facile One-Pot Approach to the Fabrication of Nanocellulose–Titanium Dioxide Nanocomposites with Promising Photocatalytic and Antimicrobial Activity

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The combination of cellulosic materials and metal oxide semiconductors can provide composites with superior functional properties compared to cellulose. By using nanocellulose derived from agricultural waste, we propose a one-pot and environmentally friendly approach to the synthesis of nanocellulose-TiO₂ (NC-TiO₂) nanocomposites with peculiar photocatalytic activity and antibacterial effects. The as-prepared NC-TiO₂ composites were fully characterized by different techniques, such as X-ray diffraction (XRD), μ-Raman, Fourier transform infrared spectroscopy (FTIR), thermogravimetry analysis (TGA), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and diffuse reflectance spectroscopy (DRS). The results showed that well crystalline anatase TiO₂ nanoparticles of about 5-6 nm were obtained. The photocatalytic activity in particular was evaluated by using methyl orange (MO) solution as a target pollutant at different pH values. It was found that all the tested NC-TiO₂ nanocomposites showed stable photocatalytic activity, even after consecutive photocatalytic runs. In addition, NCT nanocomposites with higher TiO₂ content showed degradation efficiency of almost 99% towards MO after 180 min of UV illumination. Finally, NC-TiO₂ nanocomposites also showed intriguing antimicrobial properties, demonstrating to be effective against Gram-positive (Staphylococcus aureus, Bacillus subtilis) with 20-25 mm of inhibition zone and Gram-negative bacteria (Escherichia coli, Pseudomonas aeuroginosa) with 21-24 mm of inhibition zone, and fungi (Candida albicans) with 9-10 mm of inhibition zone.