High‐Temperature Particulate Matter Filtration with Resilient Yttria‐Stabilized ZrO₂ Nanofiber Sponge

Particulate matter (PM) is a major air pollutant in many regions, jeopardizing ecosystems and public health. Filtration at pollutant source is one of the most important ways to protect the environment, however, considering the high-temperature exhaust gas emissions, effective removal of PM and related pollutants from their sources remains a major challenge. In this study, a resilient, heat-resisting, and high-efficiency PM filter based on yttria-stabilized ZrO₂ (YSZ) nanofiber sponge produced with a scalable solution blow spinning process is reported. The porous 3D sponge composed of YSZ nanofibers is lightweight (density of 20 mg cm⁻³ ) and resilient at both room temperature and high temperatures. At room-temperature conditions, the YSZ nanofiber sponge exhibits 99.4% filtration efficiency for aerosol particles with size in the range of 20-600 nm, associated with a low pressure drop of only 57 Pa under an airflow velocity of 4.8 cm s⁻¹ . At a high temperature of 750 °C, the ceramic sponge maintains a high filtration efficiency of 99.97% for PM0.3-2.5 under a high airflow velocity of 10 cm s⁻¹ . A practical vehicle exhaust filter to capture particles with filtration efficiency of >98.3% is also assembled. Hence, the YSZ nanofiber sponge has enormous potential to be applied in industry.