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Egg-shell, egg-yolk and egg-white types of Co/SiO2 catalysts were prepared by utilizing entrapped air to inhibit the entrance of impregnation or leaching solution into the cores of catalyst pellets during the preparation procedure; the entrapped air played the important role because the capillary pressure was reduced to a suitable range by adjusting the concentration of ethanol in the impregnation or leaching solution for a hydrophobized silica surface.
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Li et al. (2008) studied this question.
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